I believe there must be different kinds of vulcanite?
I have one particular Sav Punt Oro which I bought new from Wesley's beginning of this year. This pipe's stem will stay clean after treated with Obsidian Pipe Stem Oil as long as I don't touch it. But the moment I stick it between my teeth, the part that was in my mouth, turns yellow within minutes.
Then I have other vulcanite stems which give me little or no problems. Others turn yellow/brown after a couple of smokes but when treated with OPSO, they are back to normal again.
Do any of the brothers have an explanation for this problem?